Ultra-low noble metal doped polarizing glass and process

ABSTRACT

The invention is directed to a silver-containing polarizing boroaluminosilicate glass composition that has been doped with a noble metal selected from the group consisting of Pt, Pd, Os, Ir, Rh and Ru, including mixtures thereof, to nucleate and precipitate silver ions to silver metal without the need for a reducing atmosphere step. The invention is further directed to a method for making the glass composition of the invention. Using the composition and method of the invention, one can prepare a glass having a selected null transmission range.

PRIORITY

This application is a continuation-in-part application claiming thepriority of U.S. application Ser. No. 11/257,968 filed Oct. 24, 2005 andtitled “NEW VISIBLE POLARIZING GLASS AND PROCESS” and naming asinventors Nicholas F. Borrelli, George B. Hares, David J. McEnroe andJoseph F. Schroeder. This continuation-in-part application retains allthe foregoing as inventors and names as additional inventors SashaMarjanovic and Katherine R. Rossington.

FIELD OF THE INVENTION

The invention is directed to polarizing glasses and a method for makingsuch glasses. In particular, the invention is directed to asilver-containing glass composition and a noble metal from the groupconsisting of platinum, palladium, osmium, iridium, rhodium andruthenium, and a method for making the polarizing glass that does notrequire a reducing atmosphere step.

BACKGROUND OF THE INVENTION

A polarizing effect can be generated in glasses containing silver,copper or copper-cadmium crystals. These crystals can be precipitated ina boroaluminosilicate glasses having compositions containing suitableamounts of an indicated metal and a halogen other than fluorine.

The polarizing effect is generated in these crystal-containing glassesby stretching the glass and then exposing its surface to a reducingatmosphere, typically a hydrogen containing atmosphere. The glass isplaced under stress at a temperature above the glass annealingtemperature. This elongates the glass, and thereby elongates and orientsthe crystals. The shear stress that acts on the particles isproportional to the viscosity of the glass and the draw speed duringelongation. The restoring force that opposes the deformation by theshear force is inversely proportional to the particle radius. Hence, theoptimum conditions for producing a desired degree of particle elongationand a resulting polarizing effect at a given wavelength involves acomplex balance of a number of properties of the glass and the redrawingprocess. Once the glass has been elongated, the elongated glass articleis then exposed to a reducing atmosphere at a temperature above 120° C.,but not over 25° C. above the glass annealing point. This develops asurface layer in which at least a portion of metal halide crystalspresent in the glass are reduced to elemental silver or copper.

The use of silver halide as a polarizer material capitalizes on twoproperties of the silver halide that are (1) the liquid particle is verydeformable, and (2) it is easier to make larger and controlled particlessizes. The disadvantages of using silver halide are (1) that one cannotmake polarizers that operate at wavelengths shorter than red(approximately 650 nm) because of the refractive index of the silverhalide and (2) that the process required a hydrogen reduction step. Itis possible to stretch silver particles in glass as described in by E.H. Land in U.S. Pat. No. 2,319,816 and later by S. D. Stookey and R. J.Araujo in Applied Optics, Vol. 7, No. 5 (1968), pages 777-779. However,the problems encountered are the control of particle size anddistribution, especially for visible polarizer application where theaspect ratio of the particle is smalls, typically 1.5-2 to 1.

The production of polarizing glass, as is described in the patentreferences provided below, broadly involves the following four steps:

-   -   1. Melting a glass batch containing a source of silver, copper        or copper-cadmium and a halogen other than fluorine, and forming        a body from a melt;    -   2. Heat treating the glass body at a temperature above the glass        strain point to generate halide crystals having a size in the        range of 500-2000 Angstroms (Å);    -   3. Stressing the crystal-containing glass body at a temperature        above the glass annealing point to elongate the body and thereby        elongate and orient the crystals; and    -   4. Exposing the elongated body to a reducing atmosphere at a        temperature above 250° C. to develop a reduced surface layer on        the body that contains metal particles with an aspect ration of        at least 2:1.

Glass polarizers, the material compositions and the methods for makingthe glasses and articles made from the glasses have been described innumerous United States patents. Products and compositions are describedin U.S. Pat. Nos. 6,563,639, 6,466,297, 6,775,062, 5,729,381, 5,627,114,5,625,427, 5,517,356, 5,430,573, 4,125,404 and 2,319,816, and in U.S.Patent Application Publication No. 2005/0128588. Methods for makingpolarizing glass compositions and or compositions containing silver,and/or articles made from polarizing or silver-containing glasses havebeen described in U.S. Pat. Nos. 6,536,236, 6,298,691, 4,479,819,4,304,584, 4,282,022, 4,125,405, 4,188,214, 4,057,408, 4,017,316, and3,653,863. Glass articles that are polarizing at infrared wavelengthshave been described in U.S. Pat. Nos. 5,430,573, 5,332,819, 5,300,465,5,281,562, 5,275,979, 5,045,509, 4,792,535, and 4,479,819; and innon-U.S. patents or patent application publications JP 5-208844 and EP 0719 741. The Japanese patent publication describes a copper-basedpolarizing glass instead of a silver-based polarizing glass.

While there have been considerable efforts in the art to improvepolarizing glasses and the methods used to make them, there is stillconsiderable need for further improvement. In particular, it would beadvantageous to have a glass and a method for making the glass that doesnot require the use of a reducing atmosphere step. While it possible tostretch silver (Ag) particles, there are very considerable problems withregard to controlling particle size and distribution. These difficultiesare particularly pronounced regarding visible light polarizers where theaspect ratio is small, typically 1.5-2 to 1. Accordingly, it is theobject of the present invention to provide a polarizing glasscomposition that does not require a reducing atmosphere step and amethod for making such glass. In particular, it is an object of thepresent invention to provide a polarizing glass composition utilizingsilver and an additional selected noble metal, wherein the additionalnoble metal is used to nucleate atomic silver to silver metal particleswithout the use of a reducing atmosphere step, and a method for makingsuch glass.

SUMMARY OF THE INVENTION

The present invention is directed to a silver-containing polarizingboroaluminosilicate glass composition that has been doped with anadditional noble metal selected from the group consisting of platinum(Pt), palladium (Pd), gold (Au), iridium (Ir), rhodium (Rh) andruthenium (Ru), wherein the additional noble metal is used to nucleateatomic silver to form silver particles without the need for a reductionstep. In its broadest embodiment the noble metal is present at aconcentration in the range of >0 to 0.5 wt %.

The invention is further directed to visible polarizers where in oneembodiment, the noble metal, or mixture of noble metals, is present inan amount in the range of 0.0001 wt. % to 0.5 wt. % (1-5000 ppm)measured as total zero-valent noble metal. In another embodiment thenoble metal or mixture of noble metals is present in an amount in therange of 0.001 to 0.3 wt. % (10-3000 ppm). In yet a further embodimentthe noble metal or mixture of noble metals is present in an amount inthe range of 0.01 wt % to 0.3 wt %. In another embodiment the noblemetal is platinum (Pt) and is present in an amount in the range of0.0001 to 0.5 wt. %. In a further embodiment the noble metal is platinumand is present in an amount in the range of 0.001 wt. % to 0.3 wt. %. Inan addition embodiment the noble metal is platinum and is present in anamount in the range of 0.01 wt % to 0.3 wt %. The noble metal can beadded to the glass composition as a halide, nitrate or nitrite, orcomplex, for example, without limitation, acetylacetonate, oxalate andcrown ether complexes, and other complexes known in the art, or as asolution of any of the foregoing.

The invention is further directed to a silver-containingboroaluminosilicate polarizing glass composition that has been dopedwith platinum to thereby nucleate silver ions to form silver metalparticles without requiring the use of a reducing atmosphere step orother reductants known in the art such as antimony, starch, sugar orcerium.

The invention is additionally directed to a method for making asilver-containing polarizing boroaluminosilicate glass compositioncontaining silver and an additional selected noble metal, preferablyplatinum, to nucleate atomic silver to form silver particles without theuse of a reducing atmosphere step.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates the polarized transmittance spectrum of two redrawnPt-doped glass compositions having a heat treatment at temperatures of600 and 650° C., respectively, prior to drawing.

FIG. 2 illustrates transmittance in the null (“N”) and through (“T”) forthe two glasses of FIG. 1.

FIG. 3 illustrates visible light polarizer bars that have been drawn,with a finished bar on the right and an as-poured bar on the left.

FIG. 4 illustrates a glass bar after drawing on right, drawn glassribbon in the middle and a root or gob of glass from start-up.

FIG. 5 illustrates a furnace, load cell and glass bar suspended in thefurnace.

FIG. 6 illustrates an alternative furnace, load cell, downfeed and glassbar suspended in the furnace.

FIG. 7 illustrates the pulling device (tractor) system of thealternative furnace as used in attenuating the glass down during thedraw.

FIG. 8 illustrates a ribbon of glass exiting the alternative furnace andbeing drawn down.

FIG. 9 illustrates a comparison of polarized transmittance of redrawnribbon from the two different drawing systems.

FIGS. 10A-10D are an illustration comparing the absorption spectra ofglasses having different levels of Pt that have been heat treated at685° C. for different lengths of time.

DETAILED DESCRIPTION OF THE INVENTION

The term “noble metal”, as used herein with the regard to the metaldopant added to the silver containing glass, refers to the one or moremetals selected from the group consisting of platinum (Pt), palladium(Pd), gold (Au), iridium (Ir), rhodium (Rh), osmium (Os) and ruthenium(Ru). The term “noble metal” as used herein also excludes the silvercontained in the glass compositions of the invention. As also usedherein the term “ppm” means “parts-per-million by weight”.

The method of making a polarizing article by redrawing at high stress aglass containing a silver halide (“Ag X” where X is a halogen) phase iswell documented. For example, see U.S. Pat. Nos. 6,536,236, 6,298,691and 4,304,584, and other method patents cited herein. The utility ofthis process, invented by Coming Incorporated, was in the recognitionthat it was easier to elongate the silver halide particle at the sizedistribution that was formed in photochromic glass than it was toelongate a silver particle in an arbitrary glass. Once the Ag halideparticle was elongated, it was then reduced in a hydrogen-containingatmosphere to form the required elongated metallic silver particle.Although the direct elongation of a metallic silver particle ispossible, the elongation requires a much higher stress. However, thisfact does not preclude the situation where, if one finds a glasscomposition and a process where large silver crystals can becontrollably formed, that one would not be able to reduce the stressrequired to provide reasonable elongation of metallic silver particles.One advantage of the direct metallic silver particle elongation processis that in the resulting product the material surrounding the silver hasa lower refractive index relative to the bulk glass. This keeps thesurface plasmon resonance at a shorter wavelength, which is importantfor making polarizers that operate in the visible portion of thespectrum.

The glass composition of the invention that has the property ofcontrollable large silver particles is derived from the compositionsused for gradient index lenses (see U.S. Pat. No. 6,893,991 B2). Ingradient index lens glass compositions the glass contains a highconcentration of a polarizable ion, for example, Ag⁺ or Cu²⁺, and theion can be readily ion-exchanged. In the present invention it wasimportant to have a glass composition retain some silver as atomicsilver until it can be nucleated to metallic silver is conducted asdescribed herein.

The base glass composition according to the invention contains thefollowing range of materials in weight percent [wt. %]. TABLE 1 SiO₂20-60 Al₂O₃  5-20 B₂O₃ 10-25 Ag 15-40In making the base glass composition the Si, Al and B materials can beadded as oxides and Ag is added as the nitrate or as a mixture of silvernitrate and silver peroxide. Additionally, at least one noble metal saltor salt solution is added to the base glass composition and theresulting composition is mixed. The noble metal, or mixture of noblemetals if more than one is used, is selected from the group consistingof platinum, palladium, gold, osmium, iridium and ruthenium salts, andmixtures of two or more of the foregoing. The noble metal can be addedas a halide, nitrate, nitrite, a complex (for example withoutlimitation, an acetylacetonate, diamine dihalide, oxalate or crown etheror other complex known in the art), or as a solution of any of theforegoing. In one embodiment the noble metal, or mixture of noblemetals, is present in an amount in the range of 0.0001 wt. % to 0.5 wt.% (1-5000 ppm measured as total zero-valent noble metal), and it can beadded as a halide, nitrate, nitrite, a complex (for example withoutlimitation, an acetylacetonate, diamine dihalide, oxalate or crown etheror other complex known in the art), or as a solution of any of theforegoing. In a further embodiment the noble metal is present in anamount in the range of 0.0001 to 0.3 wt. %. In an additional embodimentthe noble metal in present in an amount in the range of 0.001 to 0.3 wt%.

In a selected embodiment according to the invention, the glasscomposition according to the invention is approximately (in weightpercent ±2 wt. %): TABLE 2 SiO₂ 34 Al₂O₃ 17 B₂O₃ 14 Ag 35and the noble metal is Pt in amount in the range of 0.0001 wt. % to 0.5wt. % (measured as total zero-valent noble metal). In another selectedembodiment the glass composition is as shown in Table 2 and the noblemetal is Pt in an amount in the range of 0.0001 to 0.3 wt %. In afurther selected embodiment the glass composition is as shown in Table 2and the noble metal is Pt in an amount in the range of 0.0005 to 0.3 wt.%. In yet another embodiment the glass composition is also the same asshown in Table 2 and the Pt is present in an amount in the range of 0.02wt. % to 0.2 wt. %.

When the base glass composition alone is melted in a quartz crucible atapproximately 1350° C. for approximately 16 hours, a clear, slightlyyellow glass is produced. The slightly yellow color of the glass isindicates that substantially all of the silver is dissolved in the glasscomposition as the silver +1 ion. The glass also fluoresces underultraviolet light indicating that al least some of the silver is presentat atomic silver. Upon adding only a slight amount of a noble metal, forexample, platinum, to the base glass composition the slightly yellowcolor of the glass turns to a deep red-brown color that is indicative ofthe presence of large colloidal silver particles. Small silver particlesproduce a yellow color whereas the large particles produce a lightscattering effect in addition to the absorption. This is the appearanceof a Pt-doped glass; that is the color is deeper and darker due to thelight scattering effect. The level of Pt, or other noble metal(s),needed to induce this change is in the range of 0.0001 to 0.5 wt. %.Once the nucleation or formation of metallic silver has been carriedout, one can further increase the density of the color (that is, theamount of precipitated colloidal silver particles) by heat treating theglass to a temperature in the range of 500-800° C. for a time in therange of 5 minutes to 10 days, preferably to a temperature in the rangeof 600-750° C. for a time in the range of 10 minutes to 48 hours attemperature. This ability for further effect precipitation gives oneadditional control over the amount of silver that is present as metallicsilver crystals in the glass. In addition, a further heat treatment at atemperature in the range of 500-800° C. for a time in the range of 0.5to 6 hours enables one to grow larger silver crystals.

Once the nucleation/precipitation has been completed, the glass is thanshaped prior to drawing, for example, by molding or by cutting a glassboule into a desired shape, and Blanchard ground into bars, for examplebars that are 10 to 40 inches long, 3-4 inches wide by approximately0.25 to 0.6 inch thick. To allow higher draw forces on the glass, anetching process, or a thermal treatment, or both, is used to remove orheal surface and subsurface defects that are introduced during thegrinding process. When a glass surface is mechanically removed (forexample by grinding), many surface and/or subsurface fractures or flawscan either result or become exposed. Under an applied stress thesefractures or flaws can propagate into the glass body causing the glassto fracture. By chemically etching and/or thermally treating the glasssurface the flaws are healed by rounding out the fracture (flaw)surface, or by closing it using a thermal treatment. Thermal treatmentsare generally carried out at a temperature near (within 25-50° C.) thesoftening point of the glass composition. As an example of etching,prior to drawing the glass, the glass bar is immersed in a dilutehydrofluoric acid solution for a period of time sufficient to remove aportion of the surface to remove contamination and flaws. If deemednecessary, visual inspection, with or without the use of magnification,can be used to determine when the process is completed. The glass barsare then drawn under conditions where the draw temperature allows aglass viscosity greater than 10⁶ poise and a pulling velocity that issufficient to apply a force greater than 3500 psi (>3500 psi) toelongate the silver particles.

FIG. 1 illustrates the polarized transmittance spectrum (uncorrected forreflectance) of a redrawn Pt-doped glass having the composition given inTable 2. It was determined that at pulling velocities less than 3500 psi(<3000 psi) the elongated silver particle aspect ratio is small andtherefore the null direction transmission increases at lowerwavelengths. For a polarizing glass operating at lower wavelengths, forexample, in the visible range, this increase in null directiontransmission is undesirable. When the applied force to stretch thesilver, which force is controlled by the viscosity of the glass andvelocity of the draw speed, is greater than 3500 psi, a glass materialwith an acceptable polarizing behavior in the visible range wasobtained. Further, it is preferable to apply to the drawn glass as greata force as the mechanical strength of the glass and the equipment willpermit in order to achieve the desired elongation of the silverparticles. The unpolished glass sample illustrated in FIG. 1 had atransmission is 60% in the pass or through direction (that is, lightpassing through the glass in the direction perpendicular to thedirection of elongation) and essentially 0% transmission in the null orstop direction (that is, no light passing through the glass in thedirection parallel to the direction of elongation).

FIG. 2 illustrates on a single graph the polarized transmittancespectrum (uncorrected for reflectance) in the range of 400-800 nm(visible range) of two samples of a drawn Pt-doped glass having thecomposition given in Table 2. Sample A (illustrated by the solid line,and which is the same as the sample as illustrated in FIG. 1), was givena pre-draw heat treatment at 650° C. and Sample B (illustrated by thedashed line) was given a per-draw heat treatment at 600° C. For eachsample light transmission in the direction perpendicular (through orpass direction) and parallel (null or stop direction) to the directionof elongation of the silver particles it shown by the capital letters“T” and “N”, respectively.

FIG. 2 illustrates that one can selectively determine the wavelength orwavelength range in which light will be polarized when asilver-containing glass is doped with a noble metal, heat treated anddrawn in accordance with the invention to thereby elongate the silverparticles therein. For Sample A, the glass composition was heat treatedat 650° C. prior to drawing. As one can see from the graph,transmittance in the null direction (N) direction is essentially zero inthe range of approximately 475-550 nm. Sample B, which is the same glasscomposition as Sample A, was heat treated at 600° C. prior to drawing.For this sample the transmittance in the null direction is below 10 inthe approximate range of 425-480 nm. For both glass sample transmittancein the through (“T”) direction are similar through the range measured.This comparison illustrates the aspect of the invention which is that byuse of a noble metal in a silver containing glass, one can tailor thenull range of the glass by appropriate heat treatment prior to drawingthe glass. As a result, one is able to form a glass that selectivelypolarized a selected wavelength range. As shown in FIG. 2, bycontrolling the heat treatment one can determine the performance of aglass at a given wavelength by regulating the silver particle size. InFIG. 2, the further the null peaks are shifted to the right. The shiftof the null peak represents better elongation of the particles orgreater aspect ratio, and based on the assumption that larger particlesare easier to elongate, it is concluded that the particles in the glassare larger. Thus, the curves also show that when a glass is heat treatedat lower temperatures we have smaller particles that are more difficultto elongate during draw.

FIGS. 10A-10D are absorption spectra comparisons of high silveraluminoborosilicate glasses containing various levels of Pt. The glasseswere heat treated at 685° C. for times of 20, 25, 30, 35, 40, 45 and 50minutes, which times are represented by the letters A, B, C, D, E, F andG, respectively. The amount of Pt used for FIGS. 10A, 10B, 10C and 10Dwas 0.001, 0.01, 0.002 and 0.05 wt %, respectively. The data indicatesthat the absorption spectra for 0.001% Pt glass (the lowest level of thefour figures) has the strongest absorption. While the samples evaluatedin FIGS. 10A-10D were heat treated at 685° C. for the times indicatedabove and in the Figures, the heat treatment can be carried attemperatures in the range of 500-800° C. for times in the range of 5minutes to 10 days, recognizing that long thermal treatments would notbe very cost effective. In selected embodiments the heat treatments arecarried out at a temperature in the range of 500-800° C. for a time inthe range of 10 minutes to 48 hours. In additional selected embodimentsthe heat treatments are carried out for a time in the range of 20minutes to 24 hours at a temperature in the range of 600-750° C.

As indicated above, the 0.001% Pt glass spectrum has the strongestabsorption of all the glasses measured. It is believed that what isbeing observed is that more silver(+1) is being reduced with 0.001% Ptglass than is the case when the Pt concentration is at a higher level;for example, at a Pt concentration of 0.01% or more. Without being heldto any particular theory, it appears that lowering the Pt concentrationincreases the amount of reduced silver, and it is also believed tolessen the amount of Pt colloids. The color of the as-made glass at thehigher Pt concentrations is gray-green, while at lower levels it isyellow. This suggests that the difference observed in the as-madeglasses is the result of colloidal Pt. It has been observed that evenwhen the glass is initially yellow, one can strike to a level of silver(Ag⁰) that exceeds the level obtained at higher Pt concentrations. Onepossible explanation is that when the Pt concentration is “high”, duringthe melting process there is a failure to reach thermodynamicequilibrium between platinum and silver, and that the resulting glasshas a higher concentration of Pt⁺⁴. The additional Pt⁺⁴, that is, theamount in excess of the thermodynamic equilibrium, results in lesssilver reduction. If this is correct, then decreasing the amount of Ptto a selected level should result in optimized silver reduction.However, if the Pt concentration is decreased too much, then theopposite effect occurs and insufficient silver is less than theoptimized level because there is insufficient Pt present.

A further advantage of the glass according to the invention that whenstretched it has both good transmission and contrast values at 535 nm(green polarizer application). Moreover, these values are attainedwithout the need for hydrogen or other reducing atmosphere treatment.The Pt-doped glass according to the invention represents a totally newglass composition for polarizer applications.

The process according to the invention was developed to allow a highthrough put of different glass compositions in order to investigatetheir potential for polarization applications using a redraw technique.The AMPL (for Corning's Advanced Material Processing Laboratory) drawtower (purchased from Heathway Ltd, now Herbert Arnold GmbH & Co. KG,Weilburg, Germany) as shown in FIG. 5 is comprised of a downfeed system,furnace 40 and pulling tractors (not illustrated) that were used tostretch-down glass bars under high tension. Various glass compositionswere melted in a crucible then poured into a bar form using a mold. Thebars were then either machined finished or used as-poured in the drawingprocess (see FIGS. 2 and 3, described below). For the testing describedherein, the bars 30 are approximately 2 inches wide by 10 to 40 incheslong, and were of varying thicknesses ranging from 0.25 to 0.60 inches.Holes were drilled on each end of the bars (see FIG. 3 illustrating oneend of a bar); one hole being used to hang the bar from a metal cylinder22 on the downfeed system and the other hole was used to grasp the barto start the drawing process. A load cell 20 was attached to a metalcylinder 22 that was held in the place in the downfeed chuck 24 and theother end of the load cell supported the glass bar. The furnace 40 was agraphite resistance furnace that can span a wide temperature range. Thefurnace was controlled using a pyrometer and programmable controller.The glass bar was suspended in the furnace by a wire 26 connected to themetal cylinder 22 plus load cell 20 as shown in FIG. 5.

After placing the bar in the furnace, the furnace temperature was raisedto a temperature at which the glass was soft enough to enable pull-down.For the platinum-doped glass of the invention a temperature of 725° C.was used for drawing the glass. Once the glass was initially pulleddown, the downfeed which lowers the glass bar into the furnace at acontrolled rate was started. The feed rate of lowering the glass downwas set at 13 mm/min. The tractor unit is comprised of two motor drivenbelts (located below the furnace) opposing each other and rotating inopposite directions so that the motion through the belts is downward.The distance between the belts can be set so that the glass being drawnthrough can be grasped by the belts and does not slip in the belts.

FIG. 3 illustrates visible polarizer bars that have been drawn asdescribed above. The bar on the left, colored a light yellow, is a baras-poured that was drawn without the addition of a noble metal and thebar at the right, dark reddish-brown, is a finished bar containing noblemetal and drawn as described herein. FIG. 4 illustrates a glass bar onthe right, a drawn glass ribbon in the middle, and a root or gob ofglass on the bottom of the bar from start-up. When the bottom portion ofthe glass bar is drawn down it is a large gob (root) and has to be handdrawn down through the tractor unit, which is approximately two feetbelow the furnace bottom. Once the root of glass is passed through thetractor belts the smaller ribbon of glass is placed in between the beltsand the belts closed so that they are pulling the glass (see FIG. 5).The tractor belt speed is then set to a rate that is pulling the glassribbon down to a specific size. For the platinum doped glass of theinvention, a tractor speed of 2.04 m/minute was used. The ribbon canvary in size until all the draw parameters stabilize. In the exampleshown in FIG. 4 the final size of the ribbon was approximately 3.5 mm(0.138 in.) by 0.50 mm (0.02 in.).

The purpose of the draw is to induce a tensional force to stretch thepolarizing component in the glass, which is usually accomplished at hightensions. The load cell records the force being applied on the glass baras it is being pulled down by the tractor belts. The load being appliedon the glass can be adjusted by changing temperature, downfeed rate ortractor speed. Typically, at the start of the draw the load is small andincremental adjustments, typically by changing temperature, are made toincrease the tension on the glass. Sometimes several adjustments arerequired before a high enough tension is present on the glass. If theload is too great, the ribbon of glass will break and the start upprocess has to be repeated. Once a high load is achieved, the glassribbon is marked, the draw parameter(s) recorded, and the ribbon saved.The ribbon geometry is also recorded in order to calculate the force perarea applied on that particular piece of glass.

A second draw apparatus (the PRC draw apparatus) was used for furtherdevelopment of the silver based polarizing glass which had been used onPolarcor™ development. This draw consists of a seven zone rectangularfurnace 50, a downfeed system 52, load cell 54 (see FIG. 6) and atractor pulling unit 56 (see FIG. 7). FIGS. 6 and 7 illustrate the PRCdraw system which is similar to the AMPL system with regard toprocessing, except that the furnace and tractor are not incorporated ona tower structure. The other major difference between the two drawsystems is the seven zone furnace on the PRC system. This allows tightercontrol of the temperatures and the ability to adjust different zones toprovide the thermal profile best for drawing.

The two benefits the PRC draw is the ability to draw larger (wider) barsresulting in wider ribbon and the tractor unit allows greater pullingstresses to be applied to the glass. FIG. 8 shows a picture of theribbon exiting out of the furnace above the pulling tractor unit. Thetractor incorporates wider and longer belts to provide more surface areain contact with the ribbon which eliminates slippage in the tractor.

The procedure for drawing the glass on the PRC draw is the same asdescribed above with the AMPL draw. The draw parameters for the PRCsystem that resulted in good polarizing ribbon were in the range of 6 to8 inch/min. draw speed and a temperature between 620° C. to 650° C. Theresulting ribbon geometry is on the order of 15 to 20 mm wide and 0.8 to1.3 mm thick. Samples were collected during the draw along with the loadand draw parameters and then analyzed in a spectrophotometer.

Results from the PRC draw are shown in FIG. 9 compared to a result fromthe AMPL draw. It is seen that the Null curve is broader and has asteeper slope at longer wavelengths. This correlates to the PRC drawsystem ability to apply higher stress and elongating the silverparticles to greater extent. This result provides a wider polarizationwavelength window and a greater contrast ratio.

While the invention has been described with respect to a limited numberof embodiments, those skilled in the art, having benefit of thisdisclosure, will appreciate that other embodiments can be devised whichdo not depart from the scope of the invention as disclosed herein.Accordingly, the scope of the invention should be limited only by theattached claims.

1. A glass composition suitable for making optical polarizers, saidglass comprising: (a) a base glass composition comprising in wt. %: SiO₂20-60 Al₂O₃  5-20 B₂O₃ 10-25 Ag 15-40

and (b) a noble metal selected group the group consisting of platinum,palladium, gold, iridium, rhodium and ruthenium.
 2. The compositionaccording to claim 1, wherein said noble metal is present in the finalcomposition in an amount in the range of 0.0001 to 0.5 wt. %.
 3. Thecomposition according to claim 1, wherein said noble metal is present inthe final composition in an amount in the range of 0.0001 to 0.3 wt. %.4. The composition according to claim 1, wherein said noble metal ispresent in the final composition in an amount in the range of 0.001 to0.3 wt. %.
 5. The composition according to claim 1, wherein said noblemetal is Pt and the Pt is present in an amount in the range of 0.0001 to0.3 wt. %
 6. The composition according to claim 1, wherein said noblemetal is Pt and the Pt is present in an amount in the range of 0.001 to0.3 wt. %.
 7. A glass composition suitable for making opticalpolarizers, said glass comprising: (a) a glass composition comprising inwt. %±2 wt. %: SiO₂ 34 Al₂O₃ 17 B₂O₃ 14 Ag 35

and (b) a noble metal selected group the group consisting of platinum,palladium, gold, iridium, rhodium and ruthenium.
 8. The compositionaccording to claim 7, wherein said noble metal is present in the finalcomposition in an amount in the range of 0.0001 to 0.3 wt. %.
 9. Thecomposition according to claim 7, wherein said noble metal is present inthe final composition in an amount in the range of 0.001 to 0.3 wt. %.10. The composition according to claim 7, wherein said noble metal is Ptand the Pt is present in an amount in the range of 0.0001 to 0.3 wt. %.11. The composition according to claim 7, wherein said noble metal is Ptand the Pt is present in an amount in the range of 0.001 to 0.3 wt. %.12. A method of making a polarizing glass composition, said methodcomprising the steps of: preparing a base glass having a compositioncomprising 20-60 wt % SiO₂, 12-20 wt. % Al₂O₃, 10-25 wt. % B₂O₃, and15-40 wt. % Ag: adding to the above composition at least one noble metalsalt or complex selected from the group consisting of Pt, Pd, Rh, Au,Os, Ir and Ru salts, said noble metal salt being added in an amount onthe range of 0.0001 wt/% to 0.5 wt. % measure as zero valent metal;mixing the components and then melting them in a manor to achieve aglass having a viscosity less than 10³ poise; forming the glass into asuitable shape that allows stretching of the encapsulated silverparticles in the glass matrix; thermally conditioning the formed glassto remove residual stress; finishing the formed glass to a selectedgeometry and chemically and/or thermally treating the surface of theformed glass to remove or cure flaws or contaminants on the surfaceand/or subsurface of the glass; suspending the glass in a furnace heatedto a temperature such that the viscosity of the glass is in the range of10⁶ to 10⁸ poise, said suspension being in a manner such that thesuspended glass can be drawn; controlling the furnace temperature,downfeed rate and the pulling speed during draw such that an appliedforce greater than 3500 psi is used to elongate the silver particles;and drawing the glass under an applied force to thereby attenuate thesize of glass form and induce stress in the glass to thereby stretch thesilver particles within said glass.
 13. The method according to claim12, wherein the silver is added to the base glass composition as silvernitrate or a mixture of silver nitrate and silver peroxide.
 14. Themethod according to claim 12, wherein the noble metal is added as ahalide, a nitrate, or a noble metal complex, or as a solution of any ofthe foregoing.
 15. The method according to claim 14, wherein the noblemeal is added as a nitrate or a halide.
 16. The method according toclaim 12, wherein the density of the color is further increased byheating the glass to a temperature in the range of 500-800° C. for atime in the range of 5 minutes to 48 hours.
 17. The method according toclaim 12, wherein, optionally, said glass is subjected to an additionalthermal treatment to promote silver particulate growth, said thermaltreatment being at a temperature in the range of 600 to 700° C.